X-ray Structure and Electrochemical Properties of a Tpen-Bridged Hetero-Binuclear Complex fac-, fac-[ReVIIO3(^|^mu;-tpen)ReI(CO)3](PF6)2 where Tpen Is N, N, N', N'-Tetrakis (2-pyridylmethyl) ethylenediamine

• Tabeya Toshihiro

  Division of Chemistry, Graduate School of Science, Hokkaido University

• Abe Masaaki

  Division of Chemistry, Graduate School of Science, Hokkaido University

• Mitani Ayako

  Division of Chemistry, Graduate School of Science, Hokkaido University

• Tsuge Kiyoshi

  Division of Chemistry, Graduate School of Science, Hokkaido University

• Sasaki Yoichi

  Division of Chemistry, Graduate School of Science, Hokkaido University

書誌事項

タイトル別名

• X-ray Structure and Electrochemical Properties of a Tpen-Bridged Hetero-Binuclear Complex fac-, fac-[Re<SUB>VII</SUB>O<SUB>3</SUB>(μ-tpen)Re<SUP>I</SUP>(CO)<SUB>3</SUB>](PF<SUB>6</SUB>)<SUB>2</SUB> where Tpen Is N, N, N', N'-Tetrakis (2-pyridylmethyl) ethylenediamine

抄録

The molecular structure and electrochemical properties of the title complex, 1, are reported. Single-crystal X-ray diffraction study reveals that complex 1 consists of two distinct metal centers, fac-{ReO₃}⁺ and fac-{Re (CO) ₃}⁺, which are bridged by tpen in a k³-k³ coordination mode with a minimal metal-metal interactions (Re…Re=7.660 (1) Å). Complex 1 undergoes irreversible reduction and oxidation in 0.1 M n-Bu₄NPF₆-CH₃CN, which are associated with the two metal centers, fac-{ReO₃} and fac-{Re (CO) ₃}⁺.

収録刊行物

• Ｊｏｕｒｎａｌ　ｏｆ　Ｎｕｃｌｅａｒ　ａｎｄ　Ｒａｄｉｏｃｈｅｍｉｃａｌ　Ｓｃｉｅｎｃｅｓ

  Ｊｏｕｒｎａｌ　ｏｆ　Ｎｕｃｌｅａｒ　ａｎｄ　Ｒａｄｉｏｃｈｅｍｉｃａｌ　Ｓｃｉｅｎｃｅｓ 6 (3), 157-159, 2005

  日本放射化学会

詳細情報

• CRID: 1390282679457458944
• NII論文ID: 10025719264
• NII書誌ID: AA11948402
• DOI: 10.14494/jnrs2000.6.3_157
• COI: 1:CAS:528:DC%2BD28XjtFSjurg%3D
• ISSN: 18835813
• ISSN: 13454749
• 本文言語コード: en
• データソース種別:
  • JaLC
  • Crossref
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可