Conversion of Waste Sandstone Cake into Crystalline Zeolite X Using Alkali Fusion
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- Wajima Takaaki
- Department of Materials-Process Engineering & Applied Chemistry for Environments, Akita University
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- Munakata Kenzo
- Department of Materials-Process Engineering & Applied Chemistry for Environments, Akita University
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- Ikegami Yasuyuki
- Institute of Ocean Energy, Saga University
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Waste sandstone cake, which is discharged as industrial waste, was converted into crystalline zeolite-X using alkali fusion. The cake was transformed into a soluble phase via alkali fusion, and then agitated in distilled water at room temperature to give an intermediate solid, followed by synthesis at 80°C to give the final product. The effects of the agitation and synthesis times on the product phase were investigated with a view to obtaining a single crystalline zeolite-X. Hydroxysodalite was synthesized from the intermediate solid obtained without agitation, and with increasing agitation times for the intermediate solid, the amount of zeolite-X in the product increased, because of the increased Si content in the intermediate solid and the decrease of interference from impurities in the synthesis of zeolite crystals. The observed concentrations of Si and Al in the solution during the reaction explain the crystallization of the zeolite phase. The equilibrium adsorption capacity of the product for Sr2+ was almost the same as that of commercial zeolite-X in a low concentration Sr2+ solution, and the maximum adsorption capacity of the product, calculated using the Langmuir isotherm model, was 0.46 mmol/g.
収録刊行物
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- MATERIALS TRANSACTIONS
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MATERIALS TRANSACTIONS 51 (5), 849-854, 2010
公益社団法人 日本金属学会
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詳細情報 詳細情報について
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- CRID
- 1390001204250145152
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- NII論文ID
- 10026267283
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- NII書誌ID
- AA1151294X
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- ISSN
- 13475320
- 13459678
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- NDL書誌ID
- 10660360
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
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