First Diastereoselective Construction of Butane-Type and Butyrolactone-Type Secocyclolignane Structures

• MORITA Masao

  Faculty of Agriculture, Ehime University

• YAMAUCHI Satoshi

  Faculty of Agriculture, Ehime University

抄録

The first diastereoselective construction of butane-type and butyrolactone-type secocyclolignanes was achieved by the application of a high-valency heterobimetallic Ir–Sn complex to benzyl alcohols prepared from an Evans’s anti-aldol product. The elimination of an acetoxymethyl group to give a cinnamyl structure by using a high-valency heterobimetallic Ir–Sn complex was also observed in this study.

収録刊行物

• Ｂｉｏｓｃｉｅｎｃｅ，　Ｂｉｏｔｅｃｈｎｏｌｏｇｙ，　ａｎｄ　Ｂｉｏｃｈｅｍｉｓｔｒｙ

  Ｂｉｏｓｃｉｅｎｃｅ，　Ｂｉｏｔｅｃｈｎｏｌｏｇｙ，　ａｎｄ　Ｂｉｏｃｈｅｍｉｓｔｒｙ 73 (11), 2445-2451, 2009

  公益社団法人 日本農芸化学会

キーワード

• lignan
• secocyclolignane
• Ir–Sn complex

詳細情報

• CRID: 1390001206480619008
• NII論文ID: 10027547795
• NII書誌ID: AA10824164
• DOI: 10.1271/bbb.90401
• ISSN: 13476947
• ISSN: 09168451
• NDL書誌ID: 10459075
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I10459075
• Web Site: http://www.tandfonline.com/doi/pdf/10.1271/bbb.90401
• 本文言語コード: en
• データソース種別:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可