二核化大環状配位子錯体によって創られる多様な分子構造

• 宮里 裕二

  早稲田大学理工学術院創造理工学部

書誌事項

タイトル別名

• Polynuclear Structures Derived from Dinuclear Metal Complex with Phenol Based Macrocyclic Ligand
• 2カクカ ダイカンジョウ ハイイシ サクタイ ニ ヨッテ ツクラレル タヨウ ナ ブンシ コウゾウ

抄録

Dinuclear metal complex with phenol based dinucleating macrocyclic ligand (L^2-) derived from the [2+2] condensation of 2,6-diformyl-4-methylphenol and 1,3-diaminopropane can act as ‘complex as metal’, since axial position of the dinuclear complex is available for accepting donation from ‘another ligand’. A tetranuclear Fe(III) complex, [{Fe₂(L)(CH₃COO)}₂(μ-O)₂](PF₆)₂, was obtained by linking two {Fe₂(L)(OAc)} units with two oxo anions. In addition, a dinuclear copper (II) complex, [Cu₂(L)](ClO₄)₂, was reacted with [Cr(ox)₃]^3- and [Co(CN)₆]^3- as ‘complex as bridging ligand’, to afford [Cu₂(L)]₃[Cr(ox)₃]₂·6MeOH having a discrete octanuclear structure and [Cu₂(L)]₃[Co(CN)₆]₂·6MeOH·2DMF having 2-D grid structure, respectively.

収録刊行物

• 日本結晶学会誌

  日本結晶学会誌 52 (5), 246-249, 2010

  日本結晶学会

詳細情報

• CRID: 1390282679063085824
• NII論文ID: 10027673065
• NII書誌ID: AN00188364
• DOI: 10.5940/jcrsj.52.246
• COI: 1:CAS:528:DC%2BC3MXjtFSqsA%3D%3D
• ISSN: 18845576
• ISSN: 03694585
• NDL書誌ID: 10882216
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I10882216
• 本文言語コード: ja
• データソース種別:
  • JaLC
  • NDL
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