Polyoxomolybdate-Surfactant Hybrid Layered Crystal with Unusually Long Periodicity

• Ito Takeru

  Department of Chemistry, School of Science, Tokai University

• Mikurube Keisuke

  Department of Chemistry, School of Science, Tokai University

• Hasegawa Kimiko

  X-ray Research Laboratory, Rigaku Corporation

• Kurasawa Mariko

  Department of Chemistry and Materials Science, Tokyo Institute of Technology

• Naruke Haruo

  Chemical Resources Laboratory, Tokyo Institute of Technology

• Ozeki Tomoji

  Department of Chemistry and Materials Science, Tokyo Institute of Technology

抄録

An inoranic–organic hybrid crystal was synthesized by using polyoxomolybdate and hexadecylpyridinium surfactant. The unit cell was monoclinic having quite a long cell dimension (b = 75.0111(14) Å). The crystal structure was formed by alternative stacking of β-octamolybdate bilayers and interdigitated hexadecylpyridinium bilayers with layered periodicity of 3.75 nm, which is the largest value for polyoxometalate–surfactant hybrid crystals.

収録刊行物

• Chemistry Letters

  Chemistry Letters 40 (6), 626-628, 2011

  公益社団法人 日本化学会

キーワード

• General Chemistry

詳細情報

• CRID: 1390001204588649600
• NII論文ID: 10028244119
• NII書誌ID: AA00603318
• DOI: 10.1246/cl.2011.626
• COI: 1:CAS:528:DC%2BC3MXhtFOhsL3M
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/40/6/626/55605291/cl.2011.626.pdf
• 本文言語コード: en
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