偏極中性子回折によるコバルト錯体の磁気特性の解明

• 﨑山 博史

  山形大学

書誌事項

タイトル別名

• Polarized Neutron Diffraction Study on a Paramagnetic Cobalt Compound
• ヘンキョク チュウセイシ カイセツ ニ ヨル コバルト サクタイ ノ ジキ トクセイ ノ カイメイ

抄録

Polarized neutron diffraction (PND) investigations were conducted for a single-crystal of a dinuclear octahedral high-spin cobalt(II) complex, using the local site susceptibility tensor method. The local induced magnetic moments were observed on cobalt(II) ions, revealing an angle of 37(1)°. Previously the compound was found to show a characteristic magnetic behavior, which was thought to be due to the significant magnetic anisotropy caused by an angle between the local axes of cobalt(II) ions. The angle obtained by PND was in good agreement with the result of magnetic analysis, and PND methods were shown to be very useful for studying highly-anisotropic molecular paramagnetic compounds.

収録刊行物

• 日本結晶学会誌

  日本結晶学会誌 54 (3), 178-183, 2012

  日本結晶学会

詳細情報

• CRID: 1390001204089434112
• NII論文ID: 10030793281
• NII書誌ID: AN00188364
• DOI: 10.5940/jcrsj.54.178
• BIBCODE: 2012NKG....54..178S
• COI: 1:CAS:528:DC%2BC38Xht1ynurrK
• ISSN: 18845576
• ISSN: 03694585
• NDL書誌ID: 023875147
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I023875147
• 本文言語コード: ja
• データソース種別:
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