Synthesis of All the Stereoisomers of 6-Methyl-2-octadecanone, 14-Methyl-2-octadecanone, and 6,14-Dimethyl-2-octadecanone, Sex Pheromone Components of the Lyclene dharma dharma Moth, from the Enantiomers of Citronellal

• SHIKICHI Yasumasa

  Photosensitive Materials Research Center, Toyo Gosei Co., Ltd. Photosensitive Materials Research Center, Toyo Gosei Co., Ltd.

• MORI Kenji

  Photosensitive Materials Research Center, Toyo Gosei Co., Ltd. Photosensitive Materials Research Center, Toyo Gosei Co., Ltd.

書誌事項

タイトル別名

• Synthesis of All the Stereoisomers of 6-Methyl-2-octadecanone, 14-Methyl-2-octadecanone, and 6,14-Dimethyl-2-octadecanone, Sex Pheromone Components of the <i>Lyclene dharma dharma</i> Moth, from the Enantiomers of Citronellal

抄録

The enantiomers of citronellal were converted to all the stereoisomers of 6-methyl-2-octadecanone, 14-methyl-2-octadecanone, and 6,14-dimethyl-2-octadecanone, the female-produced sex pheromone components of the Lyclene dharma dharma moth. Three well-established procedures, the Wittig reaction, alkylation of alkynes, and acetoacetic ester synthesis, were employed for the carbon-carbon bond formation to connect the building blocks.

収録刊行物

• Ｂｉｏｓｃｉｅｎｃｅ，　Ｂｉｏｔｅｃｈｎｏｌｏｇｙ，　ａｎｄ　Ｂｉｏｃｈｅｍｉｓｔｒｙ

  Ｂｉｏｓｃｉｅｎｃｅ，　Ｂｉｏｔｅｃｈｎｏｌｏｇｙ，　ａｎｄ　Ｂｉｏｃｈｅｍｉｓｔｒｙ 76 (10), 1943-1951, 2012

  公益社団法人 日本農芸化学会

キーワード

• citronellal
• enantioselective synthesis
• <i>Lyclene dharma dharma</i>
• methyl-branched aliphatic ketone
• pheromone

詳細情報

• CRID: 1390282681455074944
• NII論文ID: 130004054020
• NII論文ID: 10031126485
• NII書誌ID: AA10824164
• DOI: 10.1271/bbb.120436
• COI: 1:STN:280:DC%2BC3s%2FjsFGltA%3D%3D
• ISSN: 13476947
• ISSN: 09168451
• NDL書誌ID: 024035959
• PubMed: 23047114
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I024035959
• Web Site: http://www.tandfonline.com/doi/pdf/10.1271/bbb.120436
• 本文言語コード: en
• データソース種別:
  • JaLC
  • NDL
  • Crossref
  • PubMed
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可