Synthesis and Crystal Structure of Bis(diphenylphosphino)methane Dipalladium(1) Complex with 2-Vinylpyridine(vpy).〔Pd2(μ-dppm)2(vpy)Cl〕ClO4

• Maekawa, Masahiko

• Munakata, Megumu

• Kuroda-Sowa, Takayoshi

• Suenaga, Yusaku

書誌事項

タイトル別名

• Synthesis and Crystal Structure of Bis(diphenylphosphino)methane Dipalladium(I) Complex with 2-Vinylpyridine (vpy). [Pd_2(μ-dppm)_2(vpy)Cl]ClO_4
• Synthesis and Crystal Structure of Bis

抄録

[Abstract] The bis(diphenylphosphino)methane dipalladium(I) complex: with 2-vinylpyridine, [Pd_2(μ-dppm)_2(vpy)Cl]ClO_4 (1) has been prepared and characterized crystallographically. Two Pd atoms are doubly bridged by two dppm ligands to form an eight-membered Pd_2P_4C_2 ring framework in a twist-chair conformation. Each Pd atoms are also coordinated by Cl^- ion and N atom of vpy ligand to provide a side-by-side conformation. The Pd-Pd distance of 2.597(2)Å is rather shorter than that (2.75Å) in the Pd metal, indicative of the existence of a direct Pd-Pd bond. On the eight-membered Pd_2C_2P_4 ring, the torsion angle of 43.2° is close to 45° and the Pd-Pd bond of 2.597(2)Å is also shorter than those in other dipalladium(I) dppm complexes. It has been experimentally found that the closer torsion angle is to 45°, the shorter Pd-Pd distance is. Complex 1 has the following crystal data: orthorhombic, P2_12_12_1, a=11.882(5), 6=11.909(7), c=38.676(5)Å, F=5473(3)Å^3, Z=4, R=0.048 and R_w=0.046.

Departmental Bulletin Paper

application/pdf

収録刊行物

• 理工学総合研究所研究報告

  理工学総合研究所研究報告 9 45-51, 1997-03-01

  近畿大学理工学総合研究所

キーワード

• palladium complexes
• bis(diphenylphosphino)methane
• 2-vinylpyridine
• crystal structures
• metal-metal bond

詳細情報

• CRID: 1050282677527924608
• NII論文ID: 110001244201
• NII書誌ID: AN10074306
• ISSN: 09162054
• NDL書誌ID: 4446091
• Web Site: https://kindai.repo.nii.ac.jp/records/11291
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I4446091
• 本文言語コード: en
• 資料種別: departmental bulletin paper
• データソース種別:
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  • NDL
  • CiNii Articles