PB15 長鎖アルキル基を有するビリン錯体の合成(化学・材料)

• 山内 貴恵

  京大院工

• 北川 進

  京大院工

• 水谷 義

  同志社大工

書誌事項

タイトル別名

• PB15 Synthesis of Bilin-Metal Complex Bearing Long Alkyl Chains.

抄録

Helical structural motifs attract great interest because they can be used as a constituent unit for memory, sensor, and display devices on the basis of their helical molecular shape. Zinc bilindione is a helical molecule, which undergoes racemization between P and M conformers in solution. In this system, coordination of a chiral guest to the zinc can induce helical chirality due to the shift in the P-M equilibrium. In zinc bilindione dimer system, binding of the chiral guest to one subunit induces its helical chirality and then this conformational change can allosterically control the helical chirality of the other unit through intramolecular interactions. One would expect that zinc bilindione is aggregated, the helical chirality induced by a small amount of guest can control the helical chirality of whole molecular aggregate. To realize such chiral amplification system, we prepared the zinc bilindione complex having long alkyl chains and examined its mesomorphic properties.

収録刊行物

• 日本液晶学会討論会講演予稿集

  日本液晶学会討論会講演予稿集 2003 (0), 387-388, 2003

  一般社団法人 日本液晶学会

詳細情報

• CRID: 1390001205688451712
• NII論文ID: 110001482355
• DOI: 10.11538/ekitou.2003.0_387
• ISSN: 24325988
• ISSN: 18803490
• 本文言語コード: ja
• データソース種別:
  • JaLC
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可