Quantitative Relationship between Soil Properties and Adsorption of Dissolved Organic Matter onto Volcanic Ash and Non-Volcanic Ash Soils

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The formation of soil organo-mineral complexes is a key reaction in the carbon cycle in soil, since organic materials acquire a resistance to decomposition due to the formation of the complexes. Adsorption of dissolved organic matter (DOM) onto soil minerals provides a model of this important process. Adsorption of DOM onto samples from Andisols, Inceptisols, and Entisols in batch experiments was compared in terms of the quantitative relationship between the soil properties and the adsorption behavior of DOM. Adsorption behavior was effectively described by a linear initial mass (IM) isotherm, indicating that the adsorption efficiency did not appreciably decline in the range studied even though a large amount of DOM was applied to the soil samples. Samples from Andisols showed a particularly high efficiency of adsorption compared with those from other soils which contained a comparable amount of organic carbon. Explanatory variables useful to predict the efficiency parameter were investigated in 2 steps: firstly the degree of carbon accumulation in the soil samples was examined, and next an index for the amount of ligand exchange sites was examined in combination with the former indices. As a result, an index comprising the total carbon/clay (or total carbon/specific surface area) ratio and the amount of hydroxy ions in the soil extracts with NaF solution was eventually detected. The former represents the degree of carbon occupation on the soil surface, and the latter the amount of ligand exchange sites on labile aluminum. Although the mechanisms involved in the adsorption varied among soils, the selected index was significantly correlated with the adsorption efficiency.

収録刊行物

  • Soil science and plant nutrition

    Soil science and plant nutrition 46(3), 559-569, 2000-09-01

    一般社団法人日本土壌肥料学会

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被引用文献:  4件中 1-4件 を表示

各種コード

  • NII論文ID(NAID)
    110001717883
  • NII書誌ID(NCID)
    AA00844314
  • 本文言語コード
    ENG
  • 資料種別
    ART
  • ISSN
    00380768
  • NDL 記事登録ID
    5512578
  • NDL 雑誌分類
    ZR7(科学技術--農林水産--農産)
  • NDL 請求記号
    Z53-G349
  • データ提供元
    CJP書誌  CJP引用  NDL  NII-ELS 
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