Formation of Dimers in Polar Gases: Contribution of Metastably Bound Molecules to the Second Virial Coefficient

• Saran Anil

  Indian Association for the Cultivation of Science

• Singh Yashwant

  Indian Association for the Cultivation of Science

• Barua A. K.

  Indian Association for the Cultivation of Science

抄録

The contribution of metastably bound double molecules to the second virial coefficient B(T) of a polar gas has been calculated by assuming the dipoles to be in the head-to-tail position. The same results can also be applied for any ‘effective’ relative orientation of the dipoles. The percentage of dimers has been calculated from the contribution of bound and metastably bound double molecules to the second virial coefficient for NH₃ and CHCl₃. The results have been compared with those obtained from the semiempirical approach of Hirschfelder, McClure and Weeks.

収録刊行物

• Ｊｏｕｒｎａｌ　ｏｆ　ｔｈｅ　Ｐｈｙｓｉｃａｌ　Ｓｏｃｉｅｔｙ　ｏｆ　Ｊａｐａｎ

  Ｊｏｕｒｎａｌ　ｏｆ　ｔｈｅ　Ｐｈｙｓｉｃａｌ　Ｓｏｃｉｅｔｙ　ｏｆ　Ｊａｐａｎ 22 (1), 77-81, 1967

  一般社団法人 日本物理学会

キーワード

• General Physics and Astronomy

詳細情報

• CRID: 1390001204192903936
• NII論文ID: 210000079856
• NII論文ID: 110001952829
• NII書誌ID: AA00704814
• DOI: 10.1143/jpsj.22.77
• BIBCODE: 1967JPSJ...22...77S
• COI: 1:CAS:528:DyaF2sXnvFOqug%3D%3D
• ISSN: 13474073
• ISSN: 00319015
• NDL書誌ID: 8501169
• Web Site: http://id.ndl.go.jp/bib/8501169
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I8501169
• Web Site: https://journals.jps.jp/doi/pdf/10.1143/JPSJ.22.77
• 本文言語コード: en
• データソース種別:
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• 抄録ライセンスフラグ: 使用不可