A Study of Amorphous Pd-Si Alloys by Mossbauer Effect of 57Fe and X-Ray Diffraction

• Ino Hiromitsu

  Institute of Industrial Science, University of Tokyo

• Nanao Susumu

  Institute of Industrial Science, University of Tokyo

• Muto Takashi

  Institute of Industrial Science, University of Tokyo

書誌事項

タイトル別名

• A Study of Amorphous Pd–Si Alloys by Mössbauer Effect of <SUP>57</SUP>Fe and X-Ray Diffraction
• Study of Amorphous Pd Si Alloys by Moss

抄録

Amorphous Pd_100−x−ySi_xFe_y alloys with the composition of x=15, 17.5, 20 and y=0, 0.3, 1 in at% were investigated. Quadrupole splitting decreases with the increase of silicon content and its extrapolated value almost coincides with that of crystalline Pd₃Si(Fe). The result represents the similarity of local atomic configuration of the both structures. Isomer shift of the amorphous alloys is in the range of 0.08∼0.13 mm/s and increases with silicon content, while that of c-Pd₃Si(Fe) is a negative value of −0.11 mm/s. The results are explained by the difference in the shielding effect of ⁵⁷Fe nucleus in both phases.<BR>The amorphous alloys are stable even after 575 hours ageing at 200°C, and crystallize to Pd₃Si above 250°C. Our results are different from those obtained by Masumoto et al. The different ageing behaviors may arise from the difference in the microstructure of the examined amorphous materials.

収録刊行物

• Ｊｏｕｒｎａｌ　ｏｆ　ｔｈｅ　Ｐｈｙｓｉｃａｌ　Ｓｏｃｉｅｔｙ　ｏｆ　Ｊａｐａｎ

  Ｊｏｕｒｎａｌ　ｏｆ　ｔｈｅ　Ｐｈｙｓｉｃａｌ　Ｓｏｃｉｅｔｙ　ｏｆ　Ｊａｐａｎ 46 (1), 63-71, 1979

  一般社団法人 日本物理学会

キーワード

• General Physics and Astronomy

詳細情報

• CRID: 1390282679167761920
• NII論文ID: 210000087971
• NII論文ID: 110001964199
• NII論文ID: 130003737621
• NII書誌ID: AA00704814
• DOI: 10.1143/jpsj.46.63
• BIBCODE: 1979JPSJ...46...63I
• COI: 1:CAS:528:DyaE1MXhslarsLw%3D
• ISSN: 13474073
• ISSN: 00319015
• NDL書誌ID: 2038454
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I2038454
• Web Site: https://journals.jps.jp/doi/pdf/10.1143/JPSJ.46.63
• 本文言語コード: en
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