Magnetization Measurements and 55Mn NMR Studies of LaNi0.5Mn0.5O3

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  • Magnetization Measurements and <SUP>55</SUP>Mn NMR Studies of LaNi<SUB>0.5</SUB>Mn<SUB>0.5</SUB>O<SUB>3</SUB>
  • Magnetization Measurements and 55Mn NMR

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Magnetization measurements and 55Mn NMR study of a system with the nominal formula LaNi1−xMnxO3 (0.0≤x≤0.5) were made. It was found that materials with 0.03≤x≤0.5 are mixtures of a Pauli paramagnet LaNiO3 and a ferromagnet LaNi0.5Mn0.5O3. The Curie temperature of LaNi0.5Mn0.5O3 was found to be 275 K. In this material, strong 55Mn NMR signals associated with Mn4+ were observed. The observed hyperfine magnetic fields are about −260 kOe, which is considerably smaller than the ones observed for the Mn4+ ions in other oxides. This smallness of the value seems to be due to the supertransferred hyperfine magnetic fields from the neighboring Ni2+ ions.

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