Optical Excitation of the Rotational Transition of Methane in Condensed Rare Gas Matrices
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- Nanba Takao
- Department of Physics, Faculty of Science, Tohoku University
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- Sagara Minoru
- Department of Physics, Faculty of Science, Tohoku University
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- Ikezawa Mikihiko
- Department of Physics, Faculty of Science, Tohoku University
書誌事項
- タイトル別名
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- Optical Excitation of the Rotational Tr
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The far-infrared optical absorption spectra of CH4 and CD4 molecules diluted in condensed Xe, Kr and Ar have been obtained at 6 K. The isotope shifts of the peak energy showed that observed absorption bands are due to rotational transitions and vibrational ones of the substituted molecules. In the Xe matrix the vibrational absorption band has not been found. The observed peak positions of the rotational transitions are compared with a theoretical calculation by Nishiyama and Yamamoto. The agreement between the experiment and the theory is good in the case of the Xe matrix but poor in the Kr and Ar matrices. The discrepancy is discussed in relation to the intensity of the vibrational band.
収録刊行物
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- Journal of the Physical Society of Japan
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Journal of the Physical Society of Japan 48 (1), 228-234, 1980
一般社団法人 日本物理学会
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詳細情報 詳細情報について
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- CRID
- 1390001204183846016
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- NII論文ID
- 210000088597
- 110001964719
- 130003896240
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- NII書誌ID
- AA00704814
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- BIBCODE
- 1980JPSJ...48..228N
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- COI
- 1:CAS:528:DyaL3cXitFCns7k%3D
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- ISSN
- 13474073
- 00319015
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- NDL書誌ID
- 2166036
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可