A Calculation of the Bandshape for the Transition to the State with Jahn-Teller and Spin-Orbit Couplings
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- Sakamoto Nobuhiko
- Department of Electronic Engineering, Utsunomiya University
書誌事項
- タイトル別名
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- Calculation of the Bandshape for the Tr
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抄録
The optical absorption bandshape for the transition from an s-like ground state to a vibronically coupled p-like set of excited states with spin-orbit coupling is calculated from a numerical approach. The vibronic energy levels and eigenstates of the p-like state are obtained by a numerical diagonalization of the Jahn-Teller plus spin-orbit operators. To explain the experimental band shape in cesium fluoride, it is essential to consider the effect of a T2g vibrational mode rather than an Eg vibrational mode. The strength of Jahn-Teller coupling and the spin-orbit coupling parameter for the F-center in cesium fluoride are estimated.
収録刊行物
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- Journal of the Physical Society of Japan
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Journal of the Physical Society of Japan 48 (2), 527-533, 1980
一般社団法人 日本物理学会
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詳細情報 詳細情報について
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- CRID
- 1390001204183160832
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- NII論文ID
- 110001964769
- 210000088653
- 130003896273
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- NII書誌ID
- AA00704814
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- BIBCODE
- 1980JPSJ...48..527S
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- COI
- 1:CAS:528:DyaL3cXhvVyntbc%3D
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- ISSN
- 13474073
- 00319015
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- NDL書誌ID
- 2168743
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
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- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可