Absorption Spectra of Pb++ Centers in Alkali Iodides

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  • Absorption Spectra of Pb<SUP>++</SUP> Centers in Alkali Iodides
  • Absorption Spectra of Pb + + Centers in

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The C band of Pb++ centers in LiI, NaI, KI and RbI crystals does not show a triplet structure at 77 K. The weak B band of KI : Pb and RbI : Pb lies at low energy side of the C band, whereas that of NaI : Pb and LiI : Pb does not appear separately from the C band. Suppression of the C bands and increasing of the splittings between the C and D′ bands are caused by substituting the host crystals in the order of RbI, KI, NaI and LiI, which is qualitatively interpreted in connection with the configuration interaction between an excited state of Pb++ and an electron transfer state. In addition, temperature sensitive band appears between C and D′ bands of NaI : Pb and LiI : Pb.

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