A Soft Acoustic Mode in the Ferroelastic Phase Transition of LaNbO4

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  • A Soft Acoustic Mode in the Ferroelastic Phase Transition of LaNbO<SUB>4</SUB>
  • A Soft Acoustic Mode in the Ferroelasti

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An anisotropic softening of the acoustic mode in the ferroelastic phase transition of LaNbO4 has been observed by the Brillouin scattering experiment. The transverse mode propagating along a direction deviated from the crystal axis by 23° in the ab-plane shows a complete softening at the transition temperature T0. The direction is parallel or normal to the ferroelastic domain boundary as predicted by the phenomenological analysis of the phase transition from 4⁄m to 2⁄m symmetry. The temperature dependence of the elastic susceptibility is well described by the classical indices γ=γ′=1 in both phases, suggesting a typical proper ferroelastic transition.

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