Orientation of Pyridine in TaS<sub>2</sub>(Py)<sub>1/2</sub>

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  • Orientation of Pyridine in TaS<SUB>2</SUB>(Py)<SUB>1⁄2</SUB>

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X-ray diffraction measurements on TaS2(Py)1⁄2 single crystals of the single phase with the layer spacing 12.03 Å showed that the intercalated pyridine molecules lay with aromatic ring planes perpendicular to the TaS2 layers, and the nitrogen atom located midway between the TaS2 layers with the long C–N axis parallel to the layers.

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