溶液反応及び水熱反応法によるバーネサイト型ナトリウムマンガン酸化物の合成

DOI Web Site Web Site 被引用文献12件 参考文献23件

書誌事項

タイトル別名
  • Synthesis of Birnessite-Type Sodium Manganese Oxides by Solution Reaction and Hydrothermal Methods
  • Synthesis of Birnessite-Type Sodium Man

この論文をさがす

抄録

A birnessite-type sodium manganese oxide with a layered structure was synthesized by the reaction of Mn(NO3)2 solution with a mixed solution of H2O2 and NaOH at room temperature. This sodium manganese oxide was hydrothermally treated in neutral, acidic and alkaline solutions at 150°C. The original samples which were synthesized at room temperature and hydrothermally treated samples were characterized by XRD, DTA-TG, FT-IR spectroscopy and chemical analysis. The formation of the birnessite-type sodium manganese oxide is dependent on the mixed mole ratio of NaOH/Mn(NO3)2. The fraction of the birnessite phase increased with increase in mixed mole ratio of NaOH/Mn(NO3)2. The birnessite-type manganese oxide has a basal spacing of 1.004nm before air-drying, but it changes to 0.724nm after the air-drying at room temperature. A well crystallized birnessite phase with a basal spacing of 0.724nm was obtained by hydrothermally treating the birnessite-type sodium manganese oxide prepared at room temperature with a NaOH solution.

収録刊行物

被引用文献 (12)*注記

もっと見る

参考文献 (23)*注記

もっと見る

キーワード

詳細情報 詳細情報について

問題の指摘

ページトップへ