ZnSb_2O_6及び(Zn_<1-x>M_x)Sb_2O_6(M=Co, Ni, Cu)焼結体の電気伝導度と熱電性 Electrical Conductivity and Thermoelectricity of ZnSb_2O_6 and (Zn_<1-x>M_x)Sb_2O_6(M=Co, Ni, Cu) Ceramics

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Author(s)

Abstract

Temperature dependence of electrical conductivity and thermoelectricity of trirutile-type ZnSb_2O_6 and (Zn, M)Sb_2O_6 (M=Co, Ni, Cu) ceramics were measured at temperatures ranging from room temperature to 800℃. All samples showed n-type behavior. The conductivity (σ) and thermoelectricity (α) of ZnSb_2O_6 were found to increase with increasing temperature and reached 10^0S・cm^<-1> and 190 μV・K^<-1> respectively, at 800℃. This behavior was explained by considering the carrier electrons to be supplied by oxygen defects and to have thermal activation characteristics. Partial substitution of Zn by Co, Ni, or Cu ions reduced the conductivity and increased the negative Seebeck coefficient. In the present system, a relationship between the apparent activation energies of conductivity and the lattice length of the c-axes of the crystal structure was observed. The measured electrical conductivities were not sufficient for practical use as thermoelectric materials.

Journal

  • Journal of the Ceramic Society of Japan

    Journal of the Ceramic Society of Japan 108(1257), 435-438, 2000-05-01

    The Ceramic Society of Japan

References:  4

  • <no title>

    BYSTROM A

    Arkiv.Kemi,Mineral Geol. 15B, 8, 1941

    Cited by (1)

  • <no title>

    CUSACK N.E.

    Proc.Phys.Soc. 72, 898-902, 1958

    Cited by (1)

  • <no title>

    MIYAYAMA M.

    J.Mater.Sci.Lett. 3, 323-324, 1984

    Cited by (1)

  • <no title>

    R. D. Shannon

    Acta Cryst A32, 751, 1976

    DOI Cited by (254)

Cited by:  2

Codes

  • NII Article ID (NAID)
    110002289827
  • NII NACSIS-CAT ID (NCID)
    AN10040326
  • Text Lang
    ENG
  • Article Type
    Journal Article
  • ISSN
    18821022
  • NDL Article ID
    5378466
  • NDL Source Classification
    ZP9(科学技術--化学・化学工業--無機化学・無機化学工業--セラミックス・窯業)
  • NDL Call No.
    Z17-249
  • Data Source
    CJP  CJPref  NDL  NII-ELS  J-STAGE 
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