ZrO<sub>2</sub>強靱化ムライトセラミックスの焼結と微構造

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タイトル別名
  • Sintering of ZrO<sub>2</sub> Toughened Mullite Ceramics and Its Microstructure
  • ZrO2 キョウジンカ ムライト セラミックス ノ ショウケツ ト ビ コウゾ

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抄録

Mullite/ZrO2 composite ceramics were fabricated from sol-gel derived powders. The effects of ZrO2 content and firing temperature on the densification and microstructure development have been investigated by means of SEM, TEM and XRD. It was clarified that the 5 to 25vol% addition of ZrO2 to mullite improved the sinter-ability. The effect is more striking in the composites containing 10 or 15vol% ZrO2. The growth of mullite grains was inhibited by dispersing ZrO2 particles. The effects were, especially, most predominant in the composite containing 15vol% ZrO2. However, in composites fired at 1650°C and above, remarkable grain growth was observed, and needle-like mullite grains having Al-rich composition appeared. These results may be ascribed to the coalescence of fine ZrO2 crystals.

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