Bi₂O₃-CdO-Al₂O₃系ガラスのサーモクロミズムとエネルギーギャップの温度依存性

• 陳 丹平

  岡山大学自然科学研究科

• 三浦 嘉也

  岡山大学環境理工学部

• 難波 徳郎

  岡山大学環境理工学部

• 尾坂 明義

  岡山大学工学部

書誌事項

タイトル別名

• Thermochromism and Temperature Dependence of the Energy Gap in Cadmium Aluminum Bismuthate Glasses
• Thermochromism and Temperature Dependen

抄録

Reversible thermochromic coloration was detected in BiO_1.5-CdO-AlO_1.5 system glasses. The relevant parameters were strongly dependent on the BiO_1.5 content. It was suggested that the weakened and more polarized Bi-O bond due to increased BiO_1.5 content enhanced the thermochromism of the glasses. The redshift of absorption edges at room temperature and the increase in the temperature coefficient of the shift with increasing BiO_1.5 content were analyzed. The thermochromic mechanism was explained in terms of the temperature dependence of the optical energy gap caused mainly by electron-phonon interaction.

収録刊行物

• Journal of the Ceramic Society of Japan (日本セラミックス協会学術論文誌)

  Journal of the Ceramic Society of Japan (日本セラミックス協会学術論文誌) 104 (1206), 79-83, 1996

  公益社団法人 日本セラミックス協会

キーワード

• Thermochromism
• Bi₂O₃-CdO-Al₂O₃ glasses
• Temperature dependence
• Electron-phonon interaction
• Nonconventional glass

詳細情報

• CRID: 1390001205278860544
• NII論文ID: 110002291315
• NII書誌ID: AN10040326
• DOI: 10.2109/jcersj.104.79
• ISSN: 18821022
• ISSN: 09145400
• NDL書誌ID: 3926668
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I3926668
• Web Site: http://www.jstage.jst.go.jp/article/jcersj1988/104/1206/104_1206_79/_pdf
• データソース種別:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可