噴霧熱分解法によるZnS-CdS系固溶体微粒子の作製

• 玉城 眞吉

  近畿大学工学部経営工学科

• 峠 登

  近畿大学工学部金属工学科

• 田上 敬一

  広島大学工学部化学工学科

• 奥山 喜久夫

  広島大学工学部化学工学科

書誌事項

タイトル別名

• Preparation of Fine Particles of ZnS-CdS Solid Solution by the Spray-Pyrolysis
• Preparation of Fine Particles of ZnS Cd

抄録

Ultrasonic spray-pyrolysis method was applied to the preparation of fine particles of solid solution in the system ZnS-CdS. An aqueous solution of zinc nitrate, cadmium nitrate and thiourea was used as a starting solution. Morphology and crystallinity of the produced particles were examined as a function of preparation conditions and their composition. Spherical particles of a hexagonal phase were obtained by the pyrolysis at around 700°C. The size of the obtained particles was distributed in the range from 0.3 to 1.5μm; each particle was found to consist of much finer crystallites. Lattice constants of the particles varied linearly with the composition, showing that solid solution particles were formed in the whole composition range of ZnS-CdS.

収録刊行物

• Journal of the Ceramic Society of Japan (日本セラミックス協会学術論文誌)

  Journal of the Ceramic Society of Japan (日本セラミックス協会学術論文誌) 104 (1206), 137-139, 1996

  公益社団法人 日本セラミックス協会

キーワード

• Spray-pyrolysis
• Fine particle
• Zn_xCd_1-xS
• Solid solution
• Thiourea complex

詳細情報

• CRID: 1390001205277075968
• NII論文ID: 110002291325
• NII書誌ID: AN10040326
• DOI: 10.2109/jcersj.104.137
• ISSN: 18821022
• ISSN: 09145400
• NDL書誌ID: 3926678
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I3926678
• Web Site: http://www.jstage.jst.go.jp/article/jcersj1988/104/1206/104_1206_137/_pdf
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