WO<sub>3</sub>を電極補助相とする高温用電気化学NO<sub>2</sub>センサー

  • GRILLI Maria Luisa
    Dipartimento di Scienze e Tecnologie Chimiche, Università di Roma “Tor Vergata,”
  • KAABBUATHONG Narin
    Dipartimento di Scienze e Tecnologie Chimiche, Università di Roma “Tor Vergata,”
  • DUTTA Atanu
    Dipartimento di Scienze e Tecnologie Chimiche, Università di Roma “Tor Vergata,”
  • BARTOLOMEO Elisaetta Di
    Dipartimento di Scienze e Tecnologie Chimiche, Università di Roma “Tor Vergata,”
  • TRAVERSA Enrico
    Dipartimento di Scienze e Tecnologie Chimiche, Università di Roma “Tor Vergata,”

書誌事項

タイトル別名
  • Electrochemical NO2 Sensors with WO3 Electrodes for High Temperature Applications.

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抄録

Electrochemical NOx sensors for high temperature applications were prepared coupling pellets of yttriastabilized zirconia (YSZ), an oxygen ion conductor, with a thick film of a semiconducting oxide (WO3) as an auxiliary phase. The obtained sensors were exposed to the same atmosphere without the use of reference air. Electromotive force (EMF), polarization curves and aperometric measurements were performed in air and at different concentrations of NO2 in air, at selected temperatures. Stable EMF values and fast response times were obtained. The sensors showed non-linear polarization curves. The role played by the electrolyte/electrode interface was determined by electrochemical impedance spectroscopy (EIS) tests: exposure to NO2 did not affect the bulk but only the electrolyte/electrode interface.

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