高分子材料　カップリング剤処理したピッチ系炭素短繊維を充てんし，酸無水物で硬化した多官能性エポキシ樹脂の動力学的性質

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タイトル別名
  • Minor Special Issue of Polymeric Materials. Dynamic Mechanical Properties of Multi-Functional Epoxy Resins Cured with Acid Anhydride, and Filled with Pitch-Based Carbon Short Fibers Treated with Coupling Agents.
  • カップリングザイ ショリシタ ピッチケイ タンソ タンセンイ オ ジュウテンシ

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Pitch-based carbon short fibers (PCF) treated with five kinds of coupling agents(CA), were added by 22.2wt% to fill three kinds of multi-functional epoxy resins cured with three kinds of acid anhydrides as hardener. Several mechanical properties of the composite materials were studied by using a Rheovibron in the temperature range from -150 to 300°C, and by using an Instron tester. The glass transition temperature(Tg) of the composites filled with CA-treated PCF (CA) was higher than that of the composites filled with untreated PCF (UT). The storage modulus (E')of the composites filled with CA-treated PCF increased also in a wide temperature range, including the glassy region at low temperature (-140°C) and room temperature (25°C), up to high temperature (200°C). However, the increase in both Tg and E' depended on the combination of epoxy resin and hardener. The values of E' of the composites at 25°C were larger than those estimated from the rule of mixture or Halpin-Tsai equation modified by Nielsen et al.. It was also found that the effect of CA-treatment on the flexural strength of composite materials was small. In the case that the matrix of composites became brittle, the effect of CA-treatment on the flexural strength appeared remarkably large. Consequently, the multi-functional epoxy resins can be made a composite material having higher heat resistant and higher modulus by filling it with CA-treated PCF.

収録刊行物

  • 材料

    材料 43 (495), 1532-1538, 1994

    公益社団法人 日本材料学会

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