瀬戸産“呉須”（磁器染付用顔料）

• 芝崎 靖雄

  名古屋工業技術試験所

• 金岡 繁人

  名古屋工業技術試験所

• 堀尾 正和

  名古屋工業技術試験所

• 渡村 信治

  名古屋工業技術試験所

• 延谷 宏治

  大阪大学産業科学研究所

• 金丸 文一

  大阪大学産業科学研究所

書誌事項

タイトル別名

• Identification of “Gosu” (Natural Pigment Containing Mn and Co) from Seto Group
• セトサン ゴス ジキ ソメツケヨウ ガンリョウ

抄録

Gosu in Seto group was studied mainly by X-ray diffractometry, analytical electron microscopy (AEM), chemical analysis, IR and DTA. Gosu consists of three crystalline phases; quartz, halloysite and lithiopholite. The results of electron microscopy and AEM showed that lithiopholite in Gosu has a plate-like shape diameter of about 4μm, and contains following metal elements; Mn (1.0), Al (0.4), Co (0.13), and Ni (0.05) (normalized in such a way that Mn-content=1). Chemical analysis showed that Gosu contains Mn (1.0), Al (0.67-0.75), Li (0.16-0.22), Co (0.11-0.58), Ni (0.20-0.22). Lithiopholite in Gosu is characterized by large amounts of Li, Al and Co ions compared with the average composition of natural lithiopholite. On heating Gosu, decomposition of lithiopholite took place at 420°C and that of halloysite at 520°C. On further heating, a spinel-type oxide and β-spodumene crystallized above 700°C and above 800°C, respectively. The lattice constant of the spinel-type oxide is 8.27Å, corresponding to that of MnAl₂O₄. Blue color of Gosu after heat treatment is attributed to the tetrahedrally coordinated Co ion which is dissolved in MnAl₂O₄.

収録刊行物

• 窯業協會誌

  窯業協會誌 92 (1064), 195-200, 1984

  公益社団法人 日本セラミックス協会

キーワード

• Gosu
• Seto group
• Lithiopholite
• Analytical electron microscopy (AEM)
• Chemical analysis

詳細情報

• CRID: 1390001205216254080
• NII論文ID: 110002313113
• NII書誌ID: AN00245650
• DOI: 10.2109/jcersj1950.92.1064_195
• ISSN: 18842127
• ISSN: 00090255
• NDL書誌ID: 2984485
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I2984485
• Web Site: http://www.jstage.jst.go.jp/article/jcersj1950/92/1064/92_1064_195/_pdf
• 本文言語コード: ja
• データソース種別:
  • JaLC
  • NDL
  • Crossref
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可