書誌事項
- タイトル別名
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- The Preparation of a Magadiite-Polyacrylonitrile Intercalation Compound and Its Conversion to Silicon Carbide
- マガディアイト ポリアクリロニトリル ソウカン カゴウブツ ノ ゴウセイ ト
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A magadiite (layered polysilicate)-polyacrylonitrile (PAN) intercalation compound was first prepared to investigate its potential as a precursor for the synthesis of non-oxide ceramics by carbothermal reduction. Acrylonitrile monomer was intercalated and polymerized in the interlayer space of a C12H25N(CH3)3-magadiite complex. After the cyclization of PAN by the heat treatment in air, the compound was heated in Ar flow for 2h. Above 1300°C, β-SiC was formed without the formation of any crystalline SiO2 phases. Since the reactions of a magadiite-carbon mixture involved the formation of cristobalite, it was shown that SiO2 from magadiite was reduced to form β-SiC without crystallization, which was caused by the presence of PAN in the interlayer space.
収録刊行物
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- 窯業協會誌
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窯業協會誌 95 (1097), 127-133, 1987
公益社団法人 日本セラミックス協会
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詳細情報 詳細情報について
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- CRID
- 1390001205248566144
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- NII論文ID
- 110002313562
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- NII書誌ID
- AN00245650
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- ISSN
- 18842127
- 00090255
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- NDL書誌ID
- 3119000
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可