非晶質から結晶化させた窒化ケイ素の焼結性と機械的性質

書誌事項

タイトル別名
  • Sintering and Mechanical Properties of Silicon Nitride Crystallized from Amorphous Powder
  • ヒショウシツ カラ ケッショウカサセタ チッカ ケイソ ノ ショウケツセイ ト
  • Effect of Yttria Addition
  • イットリア添加の影響

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抄録

The present study was conducted to clarify the effect of Y2O3 addition on the crystallization behavior of amorphous silicon nitride, the sinterability of the crystallized powder and the mechanical properties of the hot-pressed body. The results obtained are summarized as follows:<br>(1) The addition of Y2O3 promoted crystallization of amorphous Si3N4 to α-phase and the α/β transformation rate.<br>(2) When the amorphous Si3N4 powder was crystallized without additive, the resulted powder was composed of extremely elongated particles and equiaxed particles, while the powder crystallized after the addition of Y2O3 was composed of fairly small particles with uniformly distributed sizes of α- or β-phase silicon nitride.<br>(3) Considerably high mechanical strength and fracture toughness were obtained even though the crystallized silicon nitride powder was composed of mainly β-phase.<br>(4) The initial α-phase content had no significant effect on bulk density, flexural strength and KIC value, when the amorphous Si3N4 powders are crystallized with the addition of Y2O3.

収録刊行物

  • 窯業協會誌

    窯業協會誌 94 (1085), 169-176, 1986

    公益社団法人 日本セラミックス協会

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