Reduction of Alkyl(2-Oxocyclohexyl)acetates by Baker′s Yeast

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  • GANAHA Makoto
    Department of Agricultural Chemistry, Faculty of Agriculture, Ehime University
  • FUNABIKI Yuhei
    Department of Agricultural Chemistry, Faculty of Agriculture, Ehime University
  • MOTOKI Minoru
    Department of Agricultural Chemistry, Faculty of Agriculture, Ehime University
  • YAMAUCHI Satoshi
    Department of Agricultural Chemistry, Faculty of Agriculture, Ehime University
  • KINOSHITA Yoshiro
    Department of Agricultural Chemistry, Faculty of Agriculture, Ehime University

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  • Reduction of Alkyl (2-Oxocyclohexyl)acetates by Baker's Yeast.
  • Reduction of Alkyl 2-Oxocyclohexyl acet

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  Baker’s yeast reduction of methyl and ethyl (2-oxocyclohexyl)acetates proceeded with enantio- and diastereo-selectivity, affording the corresponding (2S)-trans-alcohols (major), (2S)-cis-alcohols (minor), and the unaltered (1S)-ketones with high optical purity.<br>

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