Effect on Insecticidal Activity of Substituents at the 1,4-Benzodioxanyl Moiety of Haedoxan

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著者

    • YAMAUCHI Satoshi
    • Department of Agricultural Chemistry, Faculty of Agriculture, Kyushu University
    • NAGATA Shyuichirou
    • Department of Agricultural Chemistry, Faculty of Agriculture, Kyushu University
    • TANIGUCHI Eiji
    • Department of Agricultural Chemistry, Faculty of Agriculture, Kyushu University

抄録

The haedoxan analog, (±)-2-(2,6-dimethoxyphenoxy)-1-hydroxy-6-(6-methoxy-1,4-benzodioxan-7-yl)-3,7-dioxabicyclo[3.3.0]octane, and its congeners with 2-alkoxymethyl, 2-hydroxymethyl, 2-chloro-methyl and 3-(3,4-methylenedioxyphenyl) substituents on the 1,4-benzodioxanyl group were synthesized from 6-methoxy-1,4-benzodioxan-7-carbaldehyde and its (±)-2-and 3-substituted derivatives, respectively. Some analogs were considerably insecticidal, although much less active than natural haedoxan A. The assay results suggest that 2,3-disubstitution on the 1,4-benzodioxanyl group was necessary to intensify the insecticidal activity.

収録刊行物

  • Bioscience, Biotechnology, and Biochemistry   [巻号一覧]

    Bioscience, Biotechnology, and Biochemistry 56(8), 1193-1197, 1992-08-23  [この号の目次]

    社団法人日本農芸化学会

各種コード

  • NII論文ID(NAID)
    110002680727
  • NII書誌ID(NCID)
    AA10824164
  • 本文言語コード
    ENG
  • ISSN
    09168451
  • データ提供元
    NII-ELS  J-STAGE 
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