Asymmetric Oxidation of Isopropyl Moieties of Aliphatic and Aromatic Hydrocarbons by Rhodococcus sp. 11B.

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  • Asymmetric Oxidation of Isopropyl Moieties of Aliphatic and Aromatic Hydrocarbons by<i>Rhodococcus</i>sp. 11B

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Abstract

A 2, 5-dimethylhexane (2, 5-DMH) assimilating bacterial strain, identified as Rhodococcus sp. and some Mycobacterium species, catalyzed the asymmetric oxidation of the isopropyl moiety of hydrocarbons. The 2, 5-DMH-grown Rhodococcus sp. strain 11B produced (-)-2, 5-dimethylhexanoic acid from 2, 5-DMH, and (S)-2-phenylpropionic acid and (R)-2-phenyl-1-propanol from cumene. The biodegradability of isoalkanes, which have various branching patterns, using this strain is also discussed.

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