超音波励起フェライトメッキ法によるNiZnフェライト膜の作製

書誌事項

タイトル別名
  • Preparation of NiZn Ferrite Films by Ultrasound-Enhanced Ferrite Plating
  • チョウオンパ レイキ フェライト メッキホウ ニヨル NiZn フェライト マ

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抄録

Polycrystalline films of spinel Fe3-x-yNixZnyO4 (x = 0−0.39, y = 0-0.3) were ferrite-plated from an aqueous solution (T = 75°C, pH = 6.8) of FeCl2 + NiCl2 + ZnCl2 to which an oxidizing solution of NaNO2 had been added. Low frequency (19.5 kHz, 600 W) ultrasound waves and high-frequency (1.6 MHz, 20 W) ultrasound waves were applied during plating. When the aqueous solutions were supplied intermittently, Fe3O4 (x = y = 0) films with a smooth surface were obtained only when low- and high-frequency ultrasound waves were applied simultaneously. On the other hand, supplying the aqueous solutions continuously facilitated formation of Fe3O4 films with a smooth surface during low-frequency sonication. The simultaneous sonication increased the solubility limit of Ni ions in Fe3-x-yNixZnyO4 films to x = 0.42 from the previous limit of x = 0.35 without sonication, though at a low deposition rate (4 nm/min).

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