Thio-Sugars.IV.Synthesis of Carbohydrate 1, 3-Glycol (Six-Membered) Thionocarbonates and Their Attempted O-S Rearrangement

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Abstract

Four six-membered cyclic thionocarbonates (two sec-sec and two prim-sec) were prepared and their radical-promoted O-S rearrangement reaction was examined. The results revealed that the reaction in six-membered rings is difficult compared with the simple rearrangement in five-membered rings. In the course of syntheses of the substrates, interesting acyl migration during the stannylation process occurred.

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Codes

  • NII Article ID (NAID)
    110003616079
  • NII NACSIS-CAT ID (NCID)
    AA00602100
  • Text Lang
    ENG
  • Article Type
    NOT
  • ISSN
    00092363
  • NDL Article ID
    5893058
  • NDL Source Classification
    ZS51(科学技術--薬学) // ZP1(科学技術--化学・化学工業)
  • NDL Call No.
    Z53-D167
  • Data Source
    CJP  NDL  NII-ELS  J-STAGE 
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