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3-Methyl-8,9-methylenedioxy-1H, 6H-5,10b-propano-2,3,4,4a-tetrahydrophenanthridine, i.e. homocrinane or 9-aza-methylenedioxy-des-N-morphinane, was synthesized from 2-(3,4-methylenedioxyphenyl)-5-methylcyclohexanone which is derived from safrole.
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