New methods and reagents in organic synthesis. 14. A simple efficient preparation of methyl esters with trimethylsilyldiazomethane (TMSCHN2) and its application to gas chromatographic analysis of fatty acids.

• 橋本 典夫

• 青山 豊彦

• 塩入 孝之

抄録

Trimethylsilyldiazomethane (TMSCHN₂), known as a stable and safe substitute for highly toxic and explosive diazomethane in the Arndt-Eistert synthesis and homologation of carbonyl compounds, has smoothly reacted with various carboxylic acids in methanolic benzene solution to give the corresponding methyl esters in excellent yields.

収録刊行物

• ＣＨＥＭＩＣＡＬ　＆　ＰＨＡＲＭＡＣＥＵＴＩＣＡＬ　ＢＵＬＬＥＴＩＮ

  ＣＨＥＭＩＣＡＬ　＆　ＰＨＡＲＭＡＣＥＵＴＩＣＡＬ　ＢＵＬＬＥＴＩＮ 29 (5), 1475-1478, 1981

  公益社団法人 日本薬学会

キーワード

• gas chromatographic analysis

詳細情報

• CRID: 1390282679138427136
• NII論文ID: 110003633848
• NII書誌ID: AA00602100
• DOI: 10.1248/cpb.29.1475
• COI: 1:CAS:528:DyaL3MXkvFSmt7w%3D
• ISSN: 13475223
• ISSN: 00092363
• ISSN: http://id.crossref.org/issn/00092363
• Web Site: http://www.jstage.jst.go.jp/article/cpb1958/29/5/29_5_1475/_pdf
• Web Site: https://search.jamas.or.jp/link/ui/1982192876
• 本文言語コード: en
• データソース種別:
  • JaLC
  • Crossref
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可