The Constituents of Ledebouriella seseloides WOLFF. I. Structures of Three New Chromones

• 佐々木 博

  Tsumura Laboratory

• 田口 平八郎

  Tsumura Laboratory

• 遠藤 徹

  Tsumura Laboratory

• 吉岡 一郎

  Tsumura Laboratory

抄録

Three new chromones (8,9,and 12), named 3'-O-angeloylhamaudol, ledebouriellol, and 4'-O-β-D-glucosyl-5-O-methylvisamminol, respectively, were isolated from the root and rhizoma of Ledebouriella seseloides WOLFF (Umbelliferae), together with five known coumarins (1-5) and six known chromones (6,7,10,11,13 and 14). The structures of 8,9,and 12 were elucidated as (3S)-3,4-dihydro-5-hydroxy-3-(2-methyl-2-butenyl) oxy-2,2,8-trimethyl-2H, 6H-benzo [1,2-b : 5,4-b'] dipyran-6-one, (3S)-3,4-dihydro-2,2-dimethyl-5-hydroxy-8-hydroxymethyl-3-(2-methyl-2-butenyl) oxy-2H, 6H-benzo [1,2-b : 5,4-b'] dipyran-6-one, and (2S)-2,3-dihydro-2-(1-β-D-glucopyranosyloxy-1-methylethyl)-4-methoxy-7-methyl-5H-furo [3,2-g] [1] benzopyran-5-one, respectively, by chemical and spectral studies.

収録刊行物

• Chem. Pharm. Bull.

  Chem. Pharm. Bull. 30 3555-3562, 1982

  公益社団法人日本薬学会

キーワード

• Ledebouriella seseloides
• Umbelliferae
• chromones
• coumarins
• dihydropyranochromones
• dihydrofuranochromones

詳細情報

• CRID: 1573950402114419712
• NII論文ID: 110003634124
• NII書誌ID: AA00602100
• ISSN: 00092363
• Web Site: https://search.jamas.or.jp/link/ui/1984043254
• 本文言語コード: en
• データソース種別:
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