NMR Study of Y<sub>2</sub>(Fe<sub><i>x</i></sub>Co<sub>1-<i>x</i></sub>)<sub>17</sub>and Y(Fe<sub><i>y</i></sub>Co<sub>1-<i>y</i></sub>)<sub>5</sub>

  • Inomata Koichiro
    Toshiba Research and Development Center, Tokyo Shibaura Electric Co., Ltd.

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  • NMR Study of Y<SUB>2</SUB>(Fe<I><SUB>x</SUB></I>Co<SUB>1−<I>x</I></SUB>)<SUB>17</SUB> and Y(Fe<I><SUB>y</SUB></I>Co<SUB>1−<I>y</I></SUB>)<SUB>5</SUB>

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Nuclear magnetic resonances of Y2(FexCo1−x)17 and Y(FeyCo1−y)5 are observed at liquid N2 temperature using the spin echo method. A different Y2(FexCo1−x)17 NMR behavior from that of Y(FeyCo1−y)5 is interpreted by the existence of antiferromagnetic exchange interaction of the Fe–Fe pair, with the shortest distance in Y2(FexCo1−x)17. Intensity changes with x of Y2(FexCo1−x)17 are consistent with the magnetic anisotropy behavior of the single crystal. It is also shown that replacement of Co by Fe in Y2(FexCo1−x)17 proceeds with a preference.

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