Photoluminescence Properties of Cu<SUP>+</SUP> Centers in MgS, CaS, SrS and BrS

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The detailed emission and excitation spectra and the temperature dependence of the excitation efficiency are obtained for MgS:Cu+, CaS:Cu+, SrS:Cu+ and BaS:Cu+ at various temperatures between 16 and 293 K. In the excitation spectra of all the powder phosphors, two bands assigned to the intraionic transitions in the Cu+ ion are observed. The luminescence mechanism is explained by the isolated Cu+ ion model. The temperature dependence of the excitation efficiency suggests that the Cu+ ion in CaS, SrS and BaS occupies an off-center position of the sulfur octahedron.

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詳細情報 詳細情報について

  • CRID
    1571980077294125568
  • NII論文ID
    110003902167
  • NII書誌ID
    AA10457675
  • 本文言語コード
    en
  • データソース種別
    • CiNii Articles

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