Development of Stable a-Si Solar Cells with Wide-Gap a-Si:H i-layers Deposited by an Inert Gas Plasma Treatment Method.

  • Maruyama Eiji
    New Materials Research Center, Sanyo Electric Co., Ltd., 1–18–13 Hashiridani, Hirakata, Osaka 573, Japan
  • Hishikawa Yoshihiro
    New Materials Research Center, Sanyo Electric Co., Ltd., 1–18–13 Hashiridani, Hirakata, Osaka 573, Japan
  • Tanaka Makoto
    New Materials Research Center, Sanyo Electric Co., Ltd., 1–18–13 Hashiridani, Hirakata, Osaka 573, Japan
  • Kiyama Seiichi
    New Materials Research Center, Sanyo Electric Co., Ltd., 1–18–13 Hashiridani, Hirakata, Osaka 573, Japan
  • Tsuda Shinya
    New Materials Research Center, Sanyo Electric Co., Ltd., 1–18–13 Hashiridani, Hirakata, Osaka 573, Japan

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タイトル別名
  • Development of Stable a-Si Solar Cells

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抄録

The stability against light soaking of wide-gap hydrogenated amorphous silicon (a-Si:H) films and a-Si solar cells deposited by a newly developed inert gas plasma treatment method has been systematically investigated for the first time. The defect density (ND) of a-Si:H films with an optical gap (Eopt) of 1.64 eV deposited by the inert gas (He, Ar, Xe) plasma treatment method was measured by a constant photocurrent method (CPM). Eopt was determined by (α hν )1/3 versus hν plots. It was found that the inert gas plasma treatment method is capable of decreasing the initial and stabilized ND of the wide-gap a-Si:H films to a greater extent than that achieved by the 100% SiH4 process. In particular, the wide-gap a-Si:H film deposited using an Ar plasma treatment showed low initial and stabilized ND of about 8× 1014 cm-3 and 9× 1015 cm-3, respectively, which are comparable to those of our optimized a-Si:H with Eopt~ 1.57 eV deposited from 100% SiH4. It was also found that this deposition method is able to improve the stability of a-Si solar cells with wide-gap i-layers when compared to the 100% SiH4 process. Experimental results indicate that this deposition method can suppress the fast light-induced degradation which is probably caused by the light-induced defects that are difficult to recover by thermal annealing at ~ 150°C.

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