Stress-Induced Raman Frequency Shift in CuInSe<sub>2</sub> Thin Films Prepared by Laser Ablation

  • Taguchi Isao
    Department of Physics, Shimane Medical University, Izumo 693, Japan
  • Ezumi Hiromichi
    Department of Electrical Engineering, Hiroshima–Denki Institute of Technology, Hiroshima 739–03, Japan
  • Keitoku Susumu
    Hiroshima Women"s University, Hiroshima 734, Japan
  • Tamaru Takeyoshi
    Department of Electrical Engineering, Hiroshima–Denki Institute of Technology, Hiroshima 739–03, Japan
  • Osono Hiroto
    Department of Electrical Engineering, Hiroshima–Denki Institute of Technology, Hiroshima 739–03, Japan

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  • Stress-Induced Raman Frequency Shift in CuInSe2 Thin Films Prepared by Laser Ablation.

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Thin films of CuInSe2 have been prepared by laser ablation using a Nd:YAG laser at substrate temperatures up to 450° C. Raman scattering experiments have shown that the frequency of the A1 phonon mode for these films shifts markedly to higher frequencies similarly with CuInSe2 single crystals under compression. The existence of compressive stress in the films has been confirmed by observing the bending of a cover glass used as substrate. The magnitude and temperature dependence of the stress estimated from the frequency shifts agree with those determined from the degree of bending.

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