Effect of Hole-Doping in High-<I>T</I><SUB>c</SUB> Ln<SUB>1</SUB>Ba<SUB>2</SUB>Cu<SUB>3</SUB>O<SUB>7−δ</SUB> (Ln=Nd, La, Pr)

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Systems of solid solution Ln1−xCaxBa2Cu3O7−δ (Ln=Nd, La, Pr) have been investigated in order to clarify the effect of hole-doping on the superconducting state. The transition temperature Tc decreases with increasing Ca-ion substitution in either Nd1−xCaxBa2Cu3O7−δ or La1−xCaxBa2Cu3O7−δ. Combined with the fact that the electron-doping in the system Ln1+xBa2−xCu3O7−δ (Ln=La, Nd, Eu) decreases Tc, the experiment indicates that the nondoped LnBa2Cu3O7−δ (Ln=Nd, La) has an optimum carrier concentration for Tc. For the nonsuper-conducting Pr1−xCaxBa2Cu3O7−δ, the conductivity at 77 or 280 K exhibits a maximum at the formal valence of ca.3 for Pr1−xCax.

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詳細情報 詳細情報について

  • CRID
    1570854177335837184
  • NII論文ID
    110003928048
  • NII書誌ID
    AA10650595
  • 本文言語コード
    en
  • データソース種別
    • CiNii Articles

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