Structure and Superconducting Properties of TlCa<SUB><I>n</I>−1</SUB>Ba<SUB>2</SUB>Cu<I><SUB>n</SUB></I>O<SUB>2<I>n</I>+3</SUB> Thin Films with Zero Resistance at Temperatures above 100 K

  • Huang T. C.
    IBM Research Division, Almaden Research Center
  • Lee W. Y.
    IBM Research Division, Almaden Research Center
  • Lee V. Y.
    IBM Research Division, Almaden Research Center
  • Karimi R.
    IBM Research Division, Almaden Research Center

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New superconducting TlCan−1Ba2CunO2n+3 thin films have been analyzed by the X-ray diffraction and four-point probe techniques. The films consist mainly of a single TlCa2Ba2Cu3O9 phase or a mixture of the TlCa2Ba2O9 and TlCaBa2Cu2O7 phases with the c-axis preferentially oriented perpendicular to the film surface. The TlCa2Ba2Cu3O9 film grown on an asymmetrically cut yttrium-stabilized ZrO2 (YSZ) substrate has the highest superconducting transition with on-set Tc near 120 K and zero resistance at 116 K. The TlCa2Ba2Cu3O9 film deposited on a SrTiO3 (100) substrate has a slightly lower transition with zero resistance at 104 K probably because of stacking faults. The film composed of both the TlCa2Ba2Cu3O9 and TlCaBa2Cu2O7 phases and grown on YSZ has a double transition with on-set Tc near 118 K and 107 K, and zero resistance at 102 K.

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