マイクロ波照射下で自己発熱するポーラスな NiO-(Ce, Sm)O<sub>2</sub> 複合体の温度プロファイルと焼結性

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  • Temperature Profile and Sinterability of Self-Heating Porous NiO-(Ce, Sm)O2 Composite During Microwave Irradiation

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The microwave-assisted self-heating profile and sinterability of porous NiO-(Ce, Sm)O2 composites with 25, 50 and 75 mass% NiO, which were prepared by heating at 800-1200°C for solid oxide fuel cell applications, were investigated. The porous NiO-(Ce, Sm)O2 composites were heated to ca. 1300°C within 5 min in a microwave field. The sinterability of the self-heating NiO-(Ce, Sm)O2 composites in a microwave field was dependent upon the mixing ratio of NiO and the pre-heating temperature. A large shrinkage of over 20% was achieved for the 25 mass% NiO-containing composites microwave-heated at 1300°C for 2 h after the pre-heating at 800°C. The sinterability was comparable to that by conventional sintering at 1400°C for 2 h.<br>

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