Transport Properties of Ce<sub>2</sub>Co<sub>7</sub>B<sub>3</sub>in Magnetic Field

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  • Transport Properties of Ce2Co7B3 in Magnetic Field

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Thermopower S, resistivity ρ and magnetization M of Ce2Co7B3 have been measured in magnetic fields up to 15 T at temperature range from 2 to 1000 K. The magnetic field dependence of S(H) and ρ(H) changes drastically at spin-flop critical field HS=6.0 T in 4.2 K. A very large negative magneto-resistance is observed, 35% in 15 T at 4.0 K, suggesting large spin–spin interaction between s and d electrons. Magnetic phase transitions in temperature and field are experimentally obtained, a magnetic phase diagram is established. The S(T) measured up to 1000 K suggests that a DOS peak exists at 250 K apart from Fermi level (εF) in energy. Below HS, a negative peak exists on the S(T) curve around 20 K, which disappears suddenly at HS. The negative peak is estimated coming from a super-zone boundary on ε–k curve caused by anti-ferromagnetic periodicity. The DOS below and above HS have been estimated from experimental S(T) in terms of Mott’s two band sd scattering model.

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