Europium ions in electrolytic colored KCl:Pb2〔+〕+Eu2〔+〕 crystals

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  • Europium ions in electrolytic colored KCl:Pb^<2+> + Eu^<2+> crystals

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The crystals of KCl doped with Pb^<2+> and Eu^<2+> ions were electrolytically colored at low temperature such as 300℃ and high electric field of 4000 V/cm. The absorption, magnetic circular dichroism and photoemission spectra were studied for the crystals before and after the coloration, and compared with those of colored KCl crystals doped with Pb^<2+> and Ca^<2+> , Sr^<2+> ions. It is concluded that Eu^<2+> ions do not change the valency by the coloration. Broad infrared emission bands are observed at 1200, 1450 and 1985 nm in the electrolytically colored crystal.  PACS: 76.30 Mi; 76.30 Kg; 78.35 Fv

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