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- MURAKAMI YOSHIKO
- Department of Chemistry and Geosciences, Yamaguchi University
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- NANBA MASAFUMI
- Department of Chemistry and Geosciences, Yamaguchi University
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- TAGASHIRA SHOUJI
- Department of Chemistry and Geosciences, Yamaguchi University
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- SASAKI YOSHIAKI
- Department of Chemistry and Geosciences, Yamaguchi University
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The ion-exchange reactions of Na-magadiite with metal cations such as H+, K+, Mg2+, Ca2+, Sr2+, Ba2+, Cu2+ and Zn2+ were studied in an aqueous medium. The H+ ion and all divalent metal ions except Mg2+ exchanged with Na+ in an aqueous solution with a stoichiometric amount of the metal ion. K+ and Mg2+ showed poor reactivity with the Na-magadiite. Na+ was not fully replaced even with a K+ or Mg2+ concentration that was 100 times the Na+ concentration. The pH dependence of Cu2+ for the ion-exchange reaction was different from that of other metal ions. XRD analysis revealed that the structure of the Na-magadiite differed from the Cu-or H-magadiite. These differences arose from structural changes in the silicate sheet due to the H+ or Cu2+ adopting a different geometry in interaction with the oxygen atoms in the silicate sheet. Ethylene diamine (en) and pentaethylene hexamine (pentaen) react with Cu2+ to form stable cationic complexes: Cu (en) 2, which has a planar structure, and Cu (pentaen), which has an octahedral structure. The XRD patterns all revealed a difference between the basal spacings of the metal-magadiite and the sum of the crystalline ionic diameter of the metal and basal spacing of the H-magadiite. Na+ remained in the interlayer of the magadiite in the presence of excess complexes. The degree of dehydration of the metal cation depends on the ion-exchange reactivity of the magadiite.
収録刊行物
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- Clay Science
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Clay Science 12 (Supplement2), 37-41, 2006
一般社団法人 日本粘土学会
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詳細情報 詳細情報について
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- CRID
- 1390282679090154752
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- NII論文ID
- 110004867653
- 130004105186
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- NII書誌ID
- AA00607148
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- ISSN
- 21863555
- 00098574
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- CiNii Articles
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- 使用不可