Collision-Activated Dissociation Spectra for the Characterization of the Diels-Alder Adducts between C_<60> and Troponoids
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- Mori Akira
- Institute of Advanced Material Study Kyushu University
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- Liu Ji-Feng
- Institute of Advanced Material Study Kyushu University
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- Kato Nobuo
- Institute of Advanced Material Study Kyushu University
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- Isobe Ryuichi
- Tohwa University
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- Takeshita Hitoshi
- Tohwa University
Bibliographic Information
- Other Title
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- Collision-Activated Dissociation Spectr
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Abstract
Diels-Alder adducts of C_<60> easily cycloreverted to the starting materials by heating. This property makes it difficult to determine the molecular weight of adducts by means of mass spectrometry. We employed collision-activated dissociation spectra to characterize the Diels-Alder adducts of C_<60> with troponoids, cycloheptatriene, and 2-cycloalkenones and their acetals since the molecular peak of C_<60> as well as peaks derived from C_<60> were intense. This technique is useful for the determination of the molecular weight of thermally labile compounds.
Journal
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- 九州大学機能物質科学研究所報告
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九州大学機能物質科学研究所報告 11 (2), 77-82, 1997-12-15
Institute of Advanced Material Study Kyushu University
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Details 詳細情報について
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- CRID
- 1390290699812235520
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- NII Article ID
- 110006177519
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- NII Book ID
- AN10060378
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- ISSN
- 09143793
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- DOI
- 10.15017/7868
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- HANDLE
- 2324/7868
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- NDL BIB ID
- 4364920
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- Text Lang
- en
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- Data Source
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- JaLC
- IRDB
- NDL
- CiNii Articles
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- Abstract License Flag
- Allowed