61 ハナミョウガより得られるセスキテルペン類の構造相関について
書誌事項
- タイトル別名
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- 61 STRUCTURAL RELATIONSHIPS OF SESQUITERPENS OBTAINED FROM ALPINIA JAPONICA (THUNB.) MIQ.
抄録
The seeds of Alpinia japonica(Zingiberaceae) have been used as an aromatic stomachic under the name, "Izu-shukusha" in Japan. From the fresh rhizomes of the plant, ten new sesquiterpenes, that is, Δ^<9(10)>-eremophilene-11-ol(8), hanalpinol(11), hanalpinone (9), isohanalpinone(10), alpinenone(13), alpiniol(15), hanamyol(16), alpinolide(18), 9-hydroxy alpinolide(19), alpinolide peroxide(20) were isolated together with dihydroagarofuran(1), α-agarofuran(2), 4α-hydroxydihydroagarofuran(3), 10-epi-γ-eudesmol (4), 3α,4α-oxidoagarofuran(5), 3β,4β-oxidoagarofuran(6), β-eudesmol(7), furopelargone B(21), furopelargone A(22), and pogostol(17). Alpiniol(15) had a new skeleton which will be produced in the rearrangement of guaien-1,10-epoxide and (18)-(22) were considered to be derived from (9), (10) and (11) through a cleavage of C9-C10 bond of its guaiane skeleton. These chemical transformations may suggest the biogenesis of (18)-(22).
収録刊行物
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- 天然有機化合物討論会講演要旨集
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天然有機化合物討論会講演要旨集 27 (0), 458-465, 1985
天然有機化合物討論会実行委員会
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詳細情報 詳細情報について
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- CRID
- 1390001206073868288
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- NII論文ID
- 110006678493
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- ISSN
- 24331856
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可