Magnetically induced orientation of mesochannels inside porous anodic alumina membranes under ultra high magnetic field of 30 T: Confirmation by TEM

  • YAMAUCHI Yusuke
    World Premier International (WPI) Research Center, International Center for Materials Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS)
  • SUGIYAMA Atsushi
    Waseda Institute for Advanced Study, Waseda University
  • SAWADA Makoto
    Department of Applied Chemistry, Faculty of Science & Engineering, Waseda University
  • KOMATSU Masaki
    Department of Applied Chemistry, Faculty of Science & Engineering, Waseda University
  • TAKAI Azusa
    Department of Applied Chemistry, Faculty of Science & Engineering, Waseda University
  • URATA Chihiro
    Department of Applied Chemistry, Faculty of Science & Engineering, Waseda University
  • HIROTA Noriyuki
    World Premier International (WPI) Research Center, International Center for Materials Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS) Nanoceramics Center, National Institute for Materials Science (NIMS)
  • SAKKA Yoshio
    World Premier International (WPI) Research Center, International Center for Materials Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS) Nanoceramics Center, National Institute for Materials Science (NIMS)
  • KURODA Kazuyuki
    Department of Applied Chemistry, Faculty of Science & Engineering, Waseda University

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Abstract

Mesoporous silica rods were prepared inside the channels of porous anodic alumina membranes (PAAMs) by a solvent evaporation method using a precursor solution containing P123 block copolymers. The orientation of the mesochannels within the PAAM channels could be controlled by applying high magnetic field processing under 30 T. When the magnetic field was applied parallel to the PAAM channels, mesochannels were successfully induced parallel along the magnetic direction. Such magnetically induced mesochannels were directly confirmed by TEM observation.

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