超原子価ハロガンとその有機合成化学反応  [in Japanese] Hypervalent Halogans and Their Reactions in Organic Synthesis  [in Japanese]

    • 落合 正仁 OCHIAI Masahito
    • 徳島大学大学院ヘルスバイオサイエンス研究部精密薬品製造学分野 Department of Pharmaceutical Organic Chemistry, Institute of Health Biosciences, Graduate School of the University of Tokushima

Abstract

This review provides an overview of the chemistry of hypervalent organohalogans, organoiodanes and organobromanes, developed recently in Tokushima. Vinylic S_N2 reactions, cyclopentene syntheses via 1,5 C-H insertion of alkylidene carbenes, reductive Claisen rearrangements, oxidations with peroxy-λ^3-iodanes, iodobenzene-catalyzed oxidations, oxidative cleavage of double bonds, oxidative coupling of alcohols with alkynes, Michael additions, and transylidations are involved. These reactions mostly rely on the hyperleaving group ability of aryl-λ^3-iodanyl, -bromanyl, and -chloranyl groups.

Journal

Journal of the Pharmaceutical Society of Japan   [List of Volumes]

Journal of the Pharmaceutical Society of Japan 129(3), 321-334, 2009-03-01  [Table of Contents]

The Pharmaceutical Society of Japan

References:  83

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Codes

  • NII Article ID (NAID) :
    110007123172
  • NII NACSIS-CAT ID (NCID) :
    AN00284903
  • Text Lang :
    JPN
  • Article Type :
    REV
  • ISSN :
    00316903
  • NDL Article ID :
    10193767
  • NDL Source Classification :
    ZS51(科学技術--薬学)
  • NDL Call No. :
    Z19-411
  • DOI :
    10.1248/yakushi.129.321
  • Databases :
    CJP  NDL  NII-ELS  J-STAGE